Table of Peak Positions (cm-1) found for
Fe(acac)3 or Cr(acac)3 and possible assignments.
3090 v (C-H) of methine
2970 antisymm
2870 symmetric v (C-H) of the Me groups
1575 C=O stretching frequency (reduced double bond order)
1522 C=C perturbed
1419 inplane (CH3) deformation - degenerate
1385 inplane (CH3) deformation - symmetric
1355 " "
1272 v (C-CH3) + v (C=C)
1186 inplane (CH) + v (C-CH3)
1021 rock (CH3)
927 v (C=C) + v (C=O)
799 d (C-H) out of plane
769 d (C-H) out of plane
665 ring deformation
653 out of plane CH3-C_O
559 ring deformation + v (Fe-O)
548 ring deformation + v (Fe-O)
References:
1) D.A. Thornton, Coord. Chem. Rev., 1990, 104, 173-249
2) K. Nakamoto, Infrared and Raman Spectra of Inorganic and Coordination Compounds,
3rd edition, John Wiley & Sons, New York, 1978.
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