B(III) species
A number of interpreted spectra are available for interactive Jmol/JSpecView display
(IR) BF3 --- (R) BF3 --- overlay the two --- split overlay
(IR)B(OH)3 --- (R) B(OH)3 --- overlay the two --- split overlay
(IR) B(CN)3 --- (R) B(CN)3 --- overlay the two --- split overlay
(IR) H2FCB(CN)3 --- (R) H2FCB(CN)3 --- overlay the two --- split overlay

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The IR and Raman spectra were all simulated at WebMO.net using Gaussian. Calculations generally took under 30 seconds of processing time so easily fit into the allowed maximum limit. The line widths were set to 20 cm-1 and data exported as JCAMP-DX files in X,Y simple format. These were then converted to DIFDUP compression form using JSpecView.

Jmol was used to read the downloaded "tar" and generate the XYZVib files.


Character table for the C3h point group
E C3(z) (C3)2 σh S3 (S3)5
linear functions,
rotations
quadratic
functions
A' 1 1 1 1 1 1 Rz x2+y2, z2
E' 1
1		 e
e*		 e*
e		 1
1		 e
e*		 e*
e		 x+iy
x-iy		 (x2-y2, xy)
A'' 1 1 1 -1 -1 -1 z
E'' 1
1		 e
e*		 e*
e		 -1
-1		 -e
-e*		 -e*
-e		 Rx+iRy
Rx-iRy		 (xz, yz)
Character table for the D3h point group
E 2C3 3C'2 σh 2S3 3σv
linear,
rotations
quadratic
A'1 1 1 1 1 1 1 x2+y2, z2
A'2 1 1 -1 1 1 -1 Rz
E' 2 -1 0 2 -1 0 (x, y) (x2-y2, xy)
A''1 1 1 1 -1 -1 -1
A''2 1 1 -1 -1 -1 1 z
E'' 2 -1 0 -2 1 0 (Rx, Ry) (xz, yz)
Character table for the Cs point group
E σh linear,
rotations		 quadratic
A' 1 1 x, y, Rz x2, y2, z2, xy
A'' 1 -1 z, Rx, Ry yz, xz

References:
List of Character Tables for the various point groups

Copyright © 2019 by The Department of Chemistry, UWI, Jamaica, all rights reserved.

Created and maintained by Prof. Robert J. Lancashire,
The Department of Chemistry, University of the West Indies,
Mona Campus, Kingston 7, Jamaica.
Created February 2019. Links checked and/or last modified 27th February 2019.
URL http://wwwchem.uwimona.edu.jm/spectra/jsmol/demos/BX3.html